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Cobalt
Cobalt information, including Technical Data, Safety Data and its high purity properties, research, applications and other useful facts are discussed below. Scientific facts such as the atomic structure, ionization energy, abundance on Earth, conductivity and thermal properties are included.

Cobalt has a metallic permeability two thirds that of iron. It exists as a mixture of two allotropes over a wide temperature range. The transformation is slow and accounts in part for the wide variation in the physical properties of cobalt. It is alloyed with iron, nickel and other metals to make Alnico, an alloy of unusual magnetic strength with many important uses. Samarium-cobalt is one of the highest strength magnet alloys known. Cobalt compounds produce a brilliant and permanent blue color in ceramic glazes, glass, pottery, tiles, and enamels. Co-60 is useful as a gamma ray source. Cobalt is available as metal and compounds with purities from 99% to 99.999% (ACS grade to ultra-high purity); metals in the form of foil, sputtering target, and rod, and compounds as submicron and nanopowder.

Cobalt facts, including appearance, CAS #, and molecular formula and safety data, research and properties are

 

  Hydrogen                                 Helium
  Lithium Beryllium                     Boron Carbon Nitrogen Oxygen Fluorine Neon
  Sodium Magnesium                     Aluminum Silicon Phosphorus Sulfur Chlorine Argon
  Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
  Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
  Cesium Barium Cerium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
                                     
      Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium    
      Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium    


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available for many specific states, forms and shapes on the product pages listed to the left. Elemental or metallic forms include pellets, rod, wire and granules for evaporation source material purposes. Nanoparticles and nanopowders provide ultra high surface area which nanotechnology research and recent experiments demonstrate function to create new and unique properties and benefits.

Oxides are available in forms including powders and dense pellets for such uses as optical coating and thin film applications. Oxides tend to be insoluble. Fluorides are another insoluble form for uses in which oxygen is undesirable such as metallurgy, chemical and physical vapor deposition and in some optical coatings. Cobalt is available in soluble forms including chlorides, nitrates and acetates. These compounds are also manufactured as solutions at specified stoichiometries.

Cobalt is a Block D, Group 9, Period 4 element. The electronic configuration is [Ar] 3d7 4s2. In its elemental form cobalt's CAS number is 7440-48-4. The cobalt atom has a radius of 125.3.pm and it's Van der Waals radius is 200.pm.

All elemental metals, compounds and solutions may be synthesized in ultra high purity (e.g. 99.999%) for laboratory standards, advanced electronic, metallurgy and optical materials and other high technology advantages. Information is provided for stable (non-radioactive) isotopes. Organo-Metallic Cobalt compounds are soluble in organic or non-aqueous solvents. See Analytical Services for information on available certified chemical and physical analysis techniques including MS-ICP, X-Ray Diffraction, PSD and Surface Area (BET) analysis.

Cobalt was first discovered by George Brandt in 1737.

French Cobalt German Cobalt Italian cobalto Portuguese Cobalto Spanish cobalto Swedish Kobolt

Abundance. The following table shows the abundance of cobalt and each of its naturally occurring isotopes on Earth along with the atomic mass for each isotope.

Isotope
Atomic Mass
% Abundance on Earth
Co-59
58.933200
100

Safety Data. The safety data for cobalt metal, nanoparticles and its compounds can vary widely depending on the form. For potential hazard information, toxicity, and road, sea and air transportation limitations, such as DOT Hazard Class, DOT Number, EU Number, NFPA Health rating and RTECS Class, please see the specific material or compound referenced in the left margin.

Hardness. Cobalt is a hard, brittle metal measuring 5.5 on the Mohs Scale of mineral hardness.

Ionization Energy. The ionization energy for cobalt (the least required energy to release a single electron from the atom in it's ground state in the gas phase) is stated in the following table:

1st Ionization Energy
760.41 kJ mol-1
2nd Ionization Energy
1648.27 kJ mol-1
3rd Ionization Energy
3232.28 kJ mol-1

Conductivity. As to cobalt's electrical and thermal conductivity, the electrical conductivity measured as to electrical resistivity @ 20 �C is 6.24 μΩcm and its electronegativities (or its ability to draw electrons relative to other elements) is 1.88. The thermal conductivity of cobalt is 100 W m-1 K-1.

Thermal Properties. The melting point and boiling point for cobalt are stated below. The following chart sets forth the heat of fusion, heat of vaporization and heat of atomization.

Heat of Fusion
15.2 kJ mol-1
Heat of Vaporization
382.4 kJ mol-1
Heat of Atomization
423.082 kJ mol-1

 
Formula Atomic Number Molecular Weight Electronegativity (Pauling) Density Melting Point
Boiling Point
Vanderwaals radius
Ionic radius Energy of first ionization
Co 27 58.9332 g.mol -1 1.8 8.9 g.cm-3 at 20 °C 1495 °C 2927 °C 200.pm 0.078 nm (+2) ; 0.063 nm (+3) 760.41 kJ.mol-1

PRODUCT CATALOG U.S. Operations Submicron & Nanopowder Tolling Ultra High Purity Sputtering Target Crystal Growth Rod, Plate, Powder, etc. Foil
 
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Recent Research & Development for Cobalt

  • Characteristics of Dusts Encountered during the Production of Cemented Tungsten Carbides. Ind Health. 2008 Dec;45(6):793-803.

  • Photo-degradation of acid green dye over Co-ZSM-5 catalysts prepared by incipient wetness impregnation technique. J Hazard Mater. 2008 May 1;153(1-2):364-71. Epub 2007 Aug 28.

  • Electrochemical characterization of AISI 316L stainless steel in contact with simulated body fluid under infection conditions. J Mater Sci Mater Med. 2008 May;19(5):2137-44. Epub 2007 Nov 13.

  • Aggressive biases towards similarly coloured males in Lake Malawi cichlid fishes. Biol Lett. 2008 Apr 23;4(2):156-9.

  • A biosorption system for metal ions on Penicillium italicum - loaded on Sepabeads SP 70 prior to flame atomic absorption spectrometric determinations. J Hazard Mater. 2008 Apr 15;152(3):1171-8. Epub 2007 Aug 2.

  • A novel procedure for rapid surface functionalisation and mediator loading of screen-printed carbon electrodes. Anal Chim Acta. 2008 Apr 7;612(2):190-7. Epub 2008 Feb 16.

  • Cobalt-mediated regio- and stereoselective assembly of dienamides by hydroaminative alkyne coupling of alpha,omega-diynes. Chem Commun (Camb). 2008 Apr 7;(13):1599-601. Epub 2008 Feb 27.

  • Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(ii) having an interligand C-C sigma-bond. Dalton Trans. 2008 Apr 7;(13):1783-6. Epub 2008 Feb 20.

  • Acetylation of prostaglandin H2 synthases by aspirin is inhibited by redox cycling of the peroxidase. Biochem Pharmacol. 2008 Apr 1;75(7):1472-81. Epub 2007 Dec 27.

  • Sensitivity to implant materials in patients with total knee arthroplasties. Biomaterials. 2008 Apr;29(10):1494-500. Epub 2007 Dec 21.

  • Esterified coir pith as an adsorbent for the removal of Co(II) from aqueous solution. Bioresour Technol. 2008 Apr;99(6):2083-6. Epub 2007 Jul 3.

  • Pseudomonas aeruginosa immobilized multiwalled carbon nanotubes as biosorbent for heavy metal ions. Bioresour Technol. 2008 Apr;99(6):1563-70. Epub 2007 May 29.

  • A comparison between cobalt and linear accelerator-based treatment plans for conformal and intensity-modulated radiotherapy. Br J Radiol. 2008 Apr;81(964):304-10. Epub 2008 Feb 4.

  • Trace metal levels and some chemical parameters in herby cheese collected from south eastern Anatolia-Turkey. Environ Monit Assess. 2008 Apr;139(1-3):27-33. Epub 2007 Jun 12.

  • Cobalt supplementation promotes hypoxic tolerance and facilitates acclimatization to hypobaric hypoxia in rat brain. High Alt Med Biol. 2008 Spring;9(1):63-75.

  • Variations in astrocyte and fibroblast response due to biomaterial particulates in vitro. J Biomed Mater Res A. 2008 Apr;85(1):14-24.

  • Transfer of metallic debris from the metal surface of an acetabular cup to artificial femoral heads by scraping: comparison between alumina and cobalt-chrome heads. J Biomed Mater Res B Appl Biomater. 2008 Apr;85(1):204-9.

  • Novel application of depleted fullerene soot (DFS) as support of catalysts for low-temperature reduction of NO with CO. J Colloid Interface Sci. 2008 Apr 1;320(1):186-93. Epub 2007 Dec 15.

  • Structure and biological properties of first row d-transition metal complexes with N-substituted sulfonamides. J Enzyme Inhib Med Chem. 2008 Apr;23(2):240-51.

  • Cleaning of waste smelter slags and recovery of valuable metals by pressure oxidative leaching. J Hazard Mater. 2008 Apr 1;152(2):607-15. Epub 2007 Jul 22.

 

 

 

 

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